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  • EI
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  • 食品科學與工程領域高質量科技期刊分級目錄第一方陣T1
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中國精品科技期刊2020
詹苑麗,王凱,曹瀟,等. 羥丙基雙淀粉磷酸酯糊液的屈服應力及觸變性研究[J]. 食品工業科技,2024,45(6):100?109. doi: 10.13386/j.issn1002-0306.2023060222.
引用本文: 詹苑麗,王凱,曹瀟,等. 羥丙基雙淀粉磷酸酯糊液的屈服應力及觸變性研究[J]. 食品工業科技,2024,45(6):100?109. doi: 10.13386/j.issn1002-0306.2023060222.
ZHAN Yuanli, WANG Kai, CAO Xiao, et al. Study on Yield Stress and Thixotropy of Hydroxypropyl Distarch Phosphate Paste[J]. Science and Technology of Food Industry, 2024, 45(6): 100?109. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023060222.
Citation: ZHAN Yuanli, WANG Kai, CAO Xiao, et al. Study on Yield Stress and Thixotropy of Hydroxypropyl Distarch Phosphate Paste[J]. Science and Technology of Food Industry, 2024, 45(6): 100?109. (in Chinese with English abstract). doi: 10.13386/j.issn1002-0306.2023060222.

羥丙基雙淀粉磷酸酯糊液的屈服應力及觸變性研究

Study on Yield Stress and Thixotropy of Hydroxypropyl Distarch Phosphate Paste

  • 摘要: 為研究羥丙基雙淀粉磷酸酯(Hydroxypropyl distarch phosphate,HPDSP)糊液的屈服應力和觸變性行為,本文以不同鏈支比的玉米淀粉(CS)和蠟質玉米淀粉(WS)為原料的HPDSP為研究對象,討論了HPDSP糊液在不同溫度條件下的臨界質量分數、屈服應力及觸變特性。結果表明,HPDSP在5 ℃時的稀溶液-半稀溶液、半稀溶液-濃溶液臨界質量分數分別為3wt%和6wt%。5wt%時玉米淀粉-羥丙基雙淀粉磷酸酯(CS-HPDSP)和蠟質玉米淀粉-羥丙基雙淀粉磷酸酯(WS-HPDSP)的屈服應力與溫度相關性較低,而6wt%時兩者屈服應力隨溫度升高(至85 ℃)顯著下降了69.52%和77.95%(P<0.05)。HPDSP的觸變性受質量分數和溫度影響,5 ℃時,5wt%的CS-HPDSP和WS-HPDSP幾乎無觸變性,6wt%時觸變環面積分別為163.49和85.00 Pa/s,隨溫度升高至85 ℃,兩者分別降低86.38%和92.18%。WS-HPDSP的三段式觸變性測定(Three interval thixotropy test,3iTT)展示出的觸變性均小于CS-HPDSP,具有較好的穩定性。綜上,與CS-HPDSP相比,WS-HPDSP的屈服應力和觸變性更小。本文為HPDSP在食品中作為增稠劑的實際應用提供了理論依據。

     

    Abstract: In order to study the yield stress and thixotropic behavior of the hydroxypropyl distarch phosphate (HPDSP) paste, HPDSP respectively derived from corn starch (CS) and waxy corn starch (WS) with different ratios of amylopectin were investigated. The critical mass fractions, yield stress, and thixotropic behavior of HPDSP pastes under various temperatures were studied. The results showed that, the critical mass fractions for the transition of the HPDSP solution at 5 ℃ from dilute to semi-dilute, and from semi-dilute to concentrated were 3wt% and 6wt%, respectively. The yield stress of 5wt% corn starch-hydroxypropyl distarch phosphate (CS-HPDSP) and waxy corn starch-hydroxypropyl distarch phosphate (WS-HPDSP) paste both showed weak correlations with temperature. However, at 6wt% concentration, the yield stress significantly decreased (P<0.05) by 69.52% and 77.95% respectively at 85 ℃. Additionally, the thixotropic behavior of HPDSP was influenced by both mass fraction and temperature. At 5 ℃, 5wt% CS-HPDSP and WS-HPDSP showed limited thixotropy, while at 6wt% of mass fraction, the areas of thixotropic loops of CS-HPDSP and WS-HPDSP were 163.49 and 85.00 Pa/s, respectively, and decreased by 86.38% and 92.18% at 85 ℃, respectively. WS-HPDSP exhibited less thixotropic behavior than CS-HPDSP, and showed better stability in three interval thixotropy test (3iTT). In conclusion, WS-HPDSP showed less yield stress and thixotropy compared with CS-HPDSP. This study provides theoretical supports for practical application of HPDSP as thickening agents in food products.

     

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